Thursday, March 7, 2019

Lewis resonance structures


Although trioxygen (Ozone – O3) may seem to satisfy octet rule, each one of two Lewis structures cannot account for the O3 bond length. The Lewis structure for ozone (O3) seems to satisfy the octet rule by placing a double bond between the central atom and one of the two end O atoms. In fact, we can put the double bond at either end of the molecule, as shown below.
However, neither one of these two Lewis structures accounts for the known bond lengths in O3. Ozone experimental results showed bond length equal to 128pm which is shorter than O-O single bond and longer than O=O bond.

Instead, we can represent O3 bonds by allowing the presence of the two structures (double arrows). The two resonance structures representing the Lewis structure occur at the same time.


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