Although trioxygen
(Ozone – O3) may seem to satisfy octet rule, each one of two Lewis
structures cannot account for the O3 bond length. The Lewis
structure for ozone (O3) seems to satisfy the octet rule by placing
a double bond between the central atom and one of the two end O atoms. In fact, we
can put the double bond at either end of the molecule, as shown below.
However, neither
one of these two Lewis structures accounts for the known bond lengths in O3.
Ozone experimental results showed bond length equal to 128pm which is shorter
than O-O single bond and longer than O=O bond.
Instead, we can
represent O3 bonds by allowing the presence of the two structures (double
arrows). The two resonance structures representing the Lewis structure occur at the
same time.
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