Covalent
bonds and electronegativity:
A covalent bond
is a bond that forms due to the sharing of electrons, mostly between two
non-metals. If the sharing atoms are of the same type of element the electrons
will be shared equally. This means the electrons will spend equal times around
each atom and there will be no difference in the electronegativity between sharing
atoms (the electronegativity is the measure of the strength of an atom to draw
the bonding electrons towards itself). The molecules of the similar atoms are
considered to be non-polar. Example, the bond between H-H in H2 is
non-polar covalent and the bond to be a pure covalent bond.
If the atoms
are from different elements the electrons will spend more time around the more electronegative
atom and the molecule is considered to be polar covalent
Example of
polar covalent bonds is the bond between H and Cl in HCl. One electron is
shared between the two atoms, this electron spend more time around the chlorine
atom than around hydrogen atom.
The strength of
polar covalent lies between ionic and non-covalent bonds (ionic bond, such as the
bond between NaCl-metals and non-metals). For that, the bond strength of HCl (polar
covalent) is stronger than between H2 (non-polar covalent) and weaker than
between NaCl (ionic).
If the difference
in the electronegativity between the two bonded atoms is more than 2, the bond considered
to be ionic. If the difference in the electronegativity less than 2, the bond is
polar-covalent. If there is no difference in the electronegativity, the bond
considered to be non-polar covalent.
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